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In order to evaluate the mechanisms of transport, a dual-sites non-equilibrium model was applied to fit the breakthrough curves of Tl(I). Retardation factor (R) values of individual Tl(I) transport from model calculations were found to be higher than that of Tl(I) transport with HA and lower than that of Tl(I) transport with BSA. The fraction of instantaneous sorption sites (β) was found to decrease with increasing pH, implying nonequilibrium sorption is a main sorption mechanism of Tl(I) with pH increasing. The fundamental data obtaine