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The rapidly growing demand for lithium has resulted in a sharp increase in its price. This is due to the ubiquitous use of lithium-ion batteries (LIBs) in large-scale energy and transportation sectors as well as portable devices. Recycling of the LIBs for being the supply of critical metals hence becomes environmentally and economically viable. The presently used approaches for the recovery of spent LIBs like pyrometallurgical process can effectively recover nickel, cobalt, and copper, while lithium is usually lost in slag. Bioleaching p