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The present study shows the importance of second neighbors in realistic models of Kekulé patterned graphene, specially at surfaces.Herein, Ti3C2Tx MXene/nitrogen-doped reduced graphene oxide (MXene/N-rGO) composite as electrocatalyst was employed to construct a new electrochemical sensing platform for the determination of adrenaline (AD). The MXene/N-rGO was synthesized via a facile one-step hydrothermal method, where ethylenediamine (EDA) acted as reducing agent and nitrogen source. The doped N in rGO serves as a bridge between MXene and
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