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High-density carboxylic and aromatic functional groups on humic acid ensured that only humic acid larger than 1KDa was adsorbed by MIL-53(Al). Tryptophan-like and humic acid-like DOM were both detected in real hospital effluent, and their effects on CIP and CBZ adsorption onto MIL-53(Al) were investigated. The presence of tryptophan did not affect CBZ adsorption on MIL-53(Al) (except when coexisting with calcium ions). Conversely, tryptophan interfered with CIP adsorption. The presence of humic acid lower than 1KDa promoted the adsorption of CBZ and CIP by
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