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The experimental SERS enhancement factor (EF) is found around 1 × 109 for the Raman probe solution with 1 pM concentration. Finite Element Method (FEM) simulations are performed for estimating the possible single molecule SERS enhancement.Mercury, as a highly toxic heavy metal, can cause very serious harm to human health and even death in severe cases. Therefore, we synthesized a novel ratiometric fluorescent probe for detecting mercury ions, with mercaptoethanol as the recognition receptor. Probe CMER could determine mercury ions in 0-1.6
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