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Experimental dimensions reveal that the air and titanium vacancies are formed under 550 °C/Ar and 350 °C/air calcination conditions, correspondingly. These air and titanium vacancies notably boost the transportation of interfacial providers, and thus significantly enhance the photocurrent shows, the evident quantum yield, and photocatalysis such photocatalytic H2 production from water-splitting, photocatalytic CO2 decrease and photo-electrochemical anticorrosion o