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Surprisingly, even when the third phase is present, free energies of transfer could still be measured in the dilute phase, which is reported for the first time, to our knowledge. We hence show that the extractive power of the dense third phase is stronger than that of conventional reverse aggregates in equilibrium with excess water.The high pressure intrusion-extrusion process of different electrolyte aqueous solutions (NaCl and CaCl2, 2 M and 3 M) in a hydrophobic pure-silica LTA zeolite was investigated for energetic purposes by means