https://www.selleckchem.com/pr....oducts/pim447-lgh447
The synthesis, structure and catalytic activity of a benzene-bridged divanadium complex were comprehensively studied. The reduction of (Nacnac)VCl2 (1) (Nacnac = (2,6-iPr2C6H3NCMe)2HC) supported by β-diketiminate with potassium graphite (KC8) by employing benzene as the solvent allows access to the benzene-bridged inverted-sandwich divanadium complex (μ-η6η6-C6H6)[V(Nacnac)]2 (2a), which can catalyze alkene alkylarylation with hypervalent iodine(iii) reagents (HIRs) via decarboxylation to generate regioselectively diverse indolino
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