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Thus, ERT could be a useful technique for obtaining more homogeneous excavated glass and other materials for use as secondary resources in metal extraction and other waste recycling techniques while eliminating complicated and often costly waste sorting needs. This study focuses on the thermo-kinetic analysis of solid peanut shell waste, through dependence of the activation energy with the conversion degree. Three model-free kinetics, Kissinger (K), Friedman (Fr) and Kissinger-Akahira-Sunose (KAS), were applied to thermogravimetric (TGA)