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99 eV and 3.06 eV but almost no effect on band gap of 4.93 eV and 3.67 eV. It indicates that the quenching of Fe3+ to DCQDs may be due to the band gap caused by surface defect is changed by Fe3+. Also, DCQDs are used as probe to detect Fe3+ and used as spray ink. Thereby, the improved intercept method may provide a new direction for researching the fluorescence mechanism of carbon quantum dots.A class of cobalt-based oxides exhibits a peculiar type of transition, entangling valence and spin state degrees of freedom of 4f and 3d elements.