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As H2O2 concentration increases from nil to 1.0 mM, the value of total EE/O decreases from 0.083 to 0.003 kWh L-1, and the most energy efficient condition is determined. This study provides a new pathway for efficient decomposition of H2O2 by Fe3+ ions in an extended pH range, which is considered a facile and promising strategy for wastewater treatment.Urbanisation will be one of the 21st century's most transformative trends. By 2050, it will increase from 55% to 68%, more than doubling the urban population in South Asia and Sub-Saharan