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Optical thermometry has attracted great interest owing to its noncontact and fast responsive properties in practical applications. However, some sensing errors may occur in many optical ratiometric thermometers due to the overlap of emission peaks, suggesting the necessity of developing excellent luminescent materials. Here, we report the fabrication and characterization of Bi4Ti3O12Yb/Ho for ratiometric thermometry. Bismuth titanate was selected as the matrix due to its low phonon energy, high machinability, and satisfactory thermal st