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Kinetic studies of dye removal from aqueous solutions by the as-prepared cross-linked networks indicate that the dye removal proceeds via pseudo-second-order kinetics. The study of adsorption isotherm of the removal process indicates that the adsorption follows the Langmuir isotherm model. In this present work, we have thoroughly evaluated the influence of PEG chain length on several physical properties and toxic cationic dye removal efficiencies of thiol-norbornene photo-cross-linked networks. Copyright © 2020 American Chemical Societ