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This work prepared a few Al-containing silicates customized with natural ligands and SnO2 nanoparticles, that have been then used as catalyst in BVO and carboxylation. Characterizations revealed the morphology associated with synthesized catalyst was altered from micron-sized slim sheets to smaller blocks, then to consistent nanoparticles (size of 50 nm) getting the doped SnO2 nanoparticles with a size of 29 nm. All catalysts showed high wager area places featuring silt-like mesopores. In deciding t