https://www.selleckchem.com/
Depending on the connectivity of solubilizing oligoethyleneglycol (OEG) side chains to the π-cores of amphiphilic naphthalene and perylene bisimide dyes, self-assembly in water either occurs upon heating or cooling. Here we show that this effect originates from differences in the enwrapping capability of the π-cores by the OEG chains. Rylene bisimides bearing phenyl substituents with three OEG chains attached directly to the hydrophobic π-cores are strongly sequestered by the OEG chains. These molecules self-assemble at elevated temperatures in an entropy-d
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