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We provide a heterofunctional maleimide/methacrylamide 4-arm PEG macromer (MethMal) designed for discerning photopolymerization compatible with multiple polymer backbones. Rheology utilizing two courses of photoinitiators shows beneficial photopolymerization capabilities. Useful assays show benefits for therapeutic distribution and 3D printing without impacting cell viability.Liquid manipulation on solid areas has attracted plenty of attention for fluid collection and dr