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A significant (p less then 0.0001) linear correlation between the predicted δ66Zn values (using variations in water salinities) vs observed δ66Zn values indicates that Zn isotope ratios in water in the PRE can be useful for predicting the mixing processes in the water.Significance of reactive oxygen species (ROS) in subsurface has been increasingly documented in recent years, whereas the mechanisms controlling ROS production and distribution in subsurface remain poorly understood. Here we show that water table fluctuations regulate the