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The photocatalytic mechanism was explained in terms of the electron transfer facilitated by conventional transfer and Z-scheme. This strategy to construct such highly visible and solar active p-n heterojunctions will pave way for future opportunities for the degradation of recalcitrant pharmaceutical pollutants.In this work, the VUV, VUV/H2O2, VUV/PMS, and VUV/H2O2/PMS processes were compared with the corresponding UVC-based AOPs under identical experimental conditions for the ammonia removal. Among the examined AOPs, the VUV/H2O2/PMS d