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Meanwhile, the control polymer PIDTT-DTBT with alternating construction has also been prepared for comparison. The broadened and improved absorption, down-shifted greatest busy molecular orbital power level (EHOMO), more planar molecular geometry thus improved the aggregation into the film condition, but insignificant effect on aggregation in answer and photostability were discovered after both decreasing thiophene π-bridge in PIDTT-TBT and additional fluorination in PIDTT-TFBT. Consequently,