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Furthermore, controllable emission shade could be successfully tuned from cyan-green to orange-red throughout the warm white light region by-design method of VO43- → Eu3+ energy transfer. The thermal quenching of as-prepared phosphors could possibly be effectively mitigated by this design method. Eventually, the as-fabricated n-UV (λex = 370 nm) pumped phosphor-converted (pc) W-LED devices utilizing Rb3RV2O8 (R = Y, Lu) along with commercial phosphors demonstrate well-distributed cozy white light with a high color-rendering