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Three structure-types of great interest for (Sn 5 Sb 3 ) 3- were identified by means of quantum substance calculations, the one that matched the X-ray diffraction data, and two that which were reminiscent of fragments of known clusters. An extensive study from the isoelectronic series of clusters, (Sn x Sb 8-x ) 2-x (x = 0 - 8), indicated that the relative energies of these three isomers vary notably with composition - independent of electron count - and that each is the international minimal at least o
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