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This work proposes a dual-cross-linked gel solid electrolyte (SE), here defined as Zn-re-inforced sodium alginate-polyacrylamide SE (Zn-reinforced SA-PAM SE), in which Na+ and Zn2+ coexist. The SE shows a high conductivity of 19.74 mS cm-1. Compared to the pure PAM gel, the tensile strength and compressive strength of Zn-reinforced SA-PAM SE are significantly enhanced to be 674.28 kPa and 16.29 MPa, respectively, because of the strengthening mechanism of Zn2+ cross-linked SA. Based on such a robust electrolyte, a novel hybrid cell is de