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High-temperature and long-term thermal stability tests demonstrate that our proposed SSA is mechanically robust and chemically stable. Moreover, a low thermal emittance (15.86%) at 500 °C promotes the photothermal conversion efficiency. In addition, due to the exceptional spectral selectivity (α/ε = 92.3/6.5%), thermal robustness (550 °C for 168 h), and photothermal conversion efficiency (86.9% at 550 °C under 100 sun), it is possible for our proposed SSA to enhance the practical realization of large-area photothermal conversion applicati