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The LC-MS/MS and GC-MS/MS analytical method was developed and validated when it comes to simultaneous determination of 79 pesticide residues in pigeonpea. The LOD and LOQ for the analytical method were in the variety of 0.53 to 3.97 and 1.60 to 10.05 µg kg-1, respectively, with a correlation coefficient of more than 0.997. Average recoveries were within the range of 80 to 118.8per cent, utilizing the RSD of not as much as 15%. Dimension anxiety (Ux) for pesticides was in the