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5-2.1 ns), an increase in the S1 → S0 fluorescence yield (0.022-0.03, a decrease in the yield of S1 → T1 intersystem crossing (0.93-0.88), and an increase in the yield of S1 → S0 internal conversion (0.048-0.09. The derived rate constants for S1 decay reveal significant differences in the photophysical properties of the zinc chelates versus free base forms. The unexpected finding of a larger rate constant for internal conversion for zinc chelates versus free bases is particularly exemplary. Collectively, the findings afford fundamen
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