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Surface-adsorbed •O2- had a greater effect on the heterogeneous surface plasma reactions than the dielectric constant, and enhanced the toluene decomposition and intermediate oxidation. A possible reaction path of toluene decomposition was also proposed.Novel particle electrodes, i.e. flotation tailings particle electrode (FPE), were prepared using flotation tailings, garden soil, and soluble starch with a mass ratio of 1631, and then used in tetracycline wastewater treatment. The physicochemical properties of FPE were systematically ch