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The loss of the BiCoO2S bandgap originates from the activity of Co 3d says to a low-energy place as a result of the reduction of the Co ionicity when the less electronegative sulfur is introduced into BiCoO3 to substitute air. The thin bandgap while the large optical absorption associated with the BiCoO2S films cultivated on various substrates tend to be positive for FE-PV programs. In inclusion, the bandgap of BiCoO2S are modulated because of the doping level of sulfur, which will help us fabrica