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Ultrathin nanoplates of metastable 1T-MoS2 have been successfully stabilized and uniformly distributed on the surface of n-butyl triethyl ammonium bromide functionalized polypyrrole/graphene oxide (BTAB/PPy/GO) by a very simple hydrothermal method. BTAB as a typical kind of quaternary ammonium-type ionic liquids (ILs) played a crucial role in the formation of the obtained 1T-MoS2/BTAB/PPy/GO. It was covalently linked with PPy/GO and arranged in a highly ordered order at the solid-liquid interface of PPy/GO and H2O due to Coulombic inte