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Reverse osmosis concentrated leachate (ROCL) from landfill leachate treatment contains high amounts of refractory organics. In this study, a combination of polymerized ferric sulfate (PFS) and nanoscale zero-valent iron/peroxymonosulfate/ozone (nZVI/PMS/O3) approach was adopted to remove refractory pollutants in ROCL. The effects of coagulant species, dosage and initial pH on the pre-treatment of organics from ROCL during coagulation process were investigated. Moreover, the influences of experimental factors, including initial pH, ozone