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A higher Al uptake in CSH was observed at higher Ca/Si ratios, which indicates a stabilizing effect of calcium in the interlayer on Al uptake. The biogenic mackinawite (FeS) is a promising remover for hexavalent chromium. However, FeS is susceptible to aggregation, affecting the removal efficiency of Cr(VI). To address the aggregation of FeS, kaolinite was selected as the stabilizer to disperse biogenic FeS. Results showed that kaolinite could be used as a supporting material for biogenic FeS during the formation process, which efficien