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A hybrid arc-wire welding method based on the variable polarity plasma arc (VPPA) and variable polarity pulse metal inert-gas (VP-PMIG) was proposed for manufacturing aluminum alloys. This paper aims to clarify the decoupling control process of heat and mass transfer in the hybrid welding process. To understand the arc physics and analyze the mass transfer behavior, the hybrid arc shape and droplet cross-sectional area with different parameters were obtained by high speed video photography. Further, the melting area of the base metal wa