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The close relationship of the materials' properties and their application potential provides optimization schemes for different applications. Finally, evidence will be presented that for metavalently bonded materials interesting effects arise in reduced dimensions. In particular, the consequences for the crystallization kinetics of thin films and nanoparticles will be discussed in detail. © 2020 The Authors. Published by WILEY-VCH Verlag GmbH Co. KGaA, Weinheim.Tomato (Solanum lycopersicum) phytochemicals, which inc