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Covalency when you look at the An-Cl relationship is examined utilizing many metrics drawn from the Natural Bond Orbital, Natural Resonance Theory and Quantum Theory of Atoms-in-Molecules (QTAIM) techniques, including relationship purchase, orbital composition, orbital overlap and electron density topology data. Most metrics agree that the later An-Cl bonds are less ionic than might be anticipated based on styles in the first 50 % of the series, because of energy degeneracy-driven covalenc