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The formation of carbocations is reversible; after alkalization, the ions return to the original neutral forms. Unlike most triarylmethyl derivatives known so far, in the crystal, the triarylmethanol, para-substituted with the chiral moiety, shows a propensity for a solid-state sorting phenomenon.Dissociation processes involving phosphorus cations were investigated during laser-assisted atom probe tomography of crystalline indium phosphide (InP). This technique not only allows the formation of medium-sized phosphorus cations by means o