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We concluded that the HCRNF via HCl modification in this work has a great application potential as slow released N fertilizer in sustainable green agriculture.Modulating microbial electron transfer during anaerobic digestion can significantly improve syntrophic interactions for enhanced biogas production. As a carbonaceous conductive material, zeolite imidazolate framework-67 (ZIF-67)-derived porous carbon (PC) was hypothesized to act as a microbial electron transfer highway and assessed with respect to understanding the fluorimetric and