https://www.selleckchem.com/pr....oducts/resiquimod.ht
A multicomponent reaction of triazoloketones, primary amines, and 4-nitrophenyl azide was developed for the synthesis of hitherto unknown angularly fused/linear bitriazoles. The two-stage mechanism was well proven by the isolation of the intermediate. This sequential reaction consists of Cornforth rearrangement and triazolization, which has also been demonstrated in a one-pot manner.The charge transport in single-molecule junctions depends critically on the chemical identity of the anchor groups that are used to connect the molecular
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