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The new composite methods have been implemented in the CRYSTAL17 code, which efficiently implements hybrid functionals and enables routine application of the new methods to large-scale calculations of such materials with excellent performance, even with small-scale computing resources.Formamidinum lead iodide perovskite is one of the most promising materials for application in solar cells due to its narrow band gap and higher thermal stability. In this work, we demonstrate the facile synthesis of square-shaped formamidinium lead iodide