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Herein, the paradigm of a novel core-shell Ag@Cu framework in situ Cu porous nanowire range skeleton (Ag@Cu NWA) is designed because the efficient cathode of an ARB. Taking advantage of the ultrathin material Ag shell (∼7 nm) plus the high-conductivity steel Cu core, combined with powerful porous nanowire framework, the as-obtained Ag@Cu NWA cathode combines the popular features of maximum utilization of the active material, superior cost transfer, and exceptional electrolyte accessibility, di