https://www.selleckchem.com/products/gdc-0068.html
A planar dibenzo-peri-hexacene derivative (2) was synthesized via FeCl3 -mediated Scholl reaction from a cyclopenta-fused perylene (CP) based polyphenylene precursor (1). However, an unexpected octagon-containing, negatively curved molecule (3) was obtained in nearly quantitative yield when 2,3-dichloro-5,6-dicyano-1,4-benzoquinone (DDQ) and methanesulfonic acid (MeSO3 H) were used. Similar results were observed when two smaller-sized precursors containing one (4) or two CP units (5) were tested. X-ray crystallographic analysis also re
Like
Comment
Share
