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The insights on the sensing electrochemistry, phase stability and sensing electrode/Li+ electrolyte structures provide first guidelines for future Li-garnet sensors to monitor a wider range of environmental pollutants and toxins.Crosslinked polymers and gels are important in soft robotics, solar vapor generation, energy storage, drug delivery, catalysis, and biosensing. However, their attractive mass transport and volume-changing abilities are diffusion-limited, requiring miniaturization to avoid slow response. Typical approaches to impro