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In this work, flexible plasticized starch/graphene oxide (PS/GO) nanocomposites are synthesized by a simple and economic solution cast technique. The structural and surface morphological study of the nanocomposite demonstrates an increased degree of interaction between PS and GO which in turn improves the mechanical strength and thermal stability of the nanocomposite. The influence of GO loading on the capacitive performance of the nanocomposite was evaluated by studying the electrochemical properties. The PS/GO nanocomposite showed an i