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This work offers a promising strategy to realize ultrathinness, excellent compatibility, high strength, as well as safe solid electrolytes for all-solid-state lithium-metal batteries.Skin-mountable devices that can directly measure various biosignals and external stimuli and communicate the information to the users have been actively studied owing to increasing demand for wearable electronics and newer healthcare systems. Research on skin-mountable devices is mainly focused on those materials and mechanical design aspects that satisfy