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2 equivalents I2. In both reactions, as the amount of I2 added increases the catalyst recyclability decreases due to catalyst instability. Low equivalents of I2 are optimal when considering both reaction rate and catalyst recyclability.A thermal-sensitive "jelly" was used to control the diffusion of a diamine monomer for synthesizing polyamide free-standing nanofilms with an adjustable thickness of 5-35 nm. The reduced reaction rate of the interfacial polymerization at the hexane-"jelly" interface made the synthesized nanofilms show hi