https://www.selleckchem.com/
The Rice-Ramsperger-Kassel-Marcus (RRKM) theory was utilized to calculate reaction kinetics and product branching ratios. The RRKM results indicate that the formation of DNB- is exclusively important in the oxidation of DCA-, whereas the same type of reaction is a minor channel in the oxidation of DCBH-. In the latter case, H2 elimination becomes dominating. The RRKM modeling also indicates that the oxidation rate constant of DCBH- is higher than that of DCA- by an order of magnitude. This rationalizes the enhanced preignition performance of DCBH- over DCA-
Like
Comment
Share
