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The physicochemical properties of solitary constituent products may possibly not be enough to meet up the needs of modern-day biotechnology development and production. To enhance materials' overall performance and broaden their applications, this work designed and tested a few titanate nanofiller (nanowire and nanotube)-enhanced polycaprolactone (PCL) composites which were 3D-printable and supplied superior mechanical properties. By grafting two various functional groups (phenyl-