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Probing the properties and components of reactive surfaces is crucial for illustrating reaction mechanisms. However, common surface analysis techniques are restricted to in situ acquisition of surface information at the molecular scale in the human environment and industrial catalysis processes. Plasmonic spectroscopies are promising tools to solve this problem. This Feature is intended to introduce the plasmonic core-shell nanoparticle enhanced spectroscopies for qualitatively and quantitatively analyzing surface trace species. Four di