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Most studies on the photodegradation of volatile organic compounds (VOCs) have focused on the synthesis of efficient photocatalysts. However, little attention has been paid to the band bending change of semiconductive photocatalysts after the adsorption of VOCs. Herein, we first disclose how the adsorption of two typical VOCs influences the band bending of P-type rutile TiO2 and consequently changes the amount of reactive radicals. This provides a new way to understand the experimental phenomenon of heterogeneous reactions. Theoretical c
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