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Reactive metals are known to electrodeposit with irregular morphological features on planar substrates. A growing body of work suggest that multiple variables - composition, mechanics, structure, ion transport properties, reductive stability, and interfacial energy of interphases formed either spontaneously or by design on the metal electrode play important but differentiated roles in regulating these morphologies. We examine the effect of fluorinated polymer thermoset coatings on Li deposition by means of experiment and theoretical line