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EG/MH/CaCO3 plays a synergetic influence on inhibiting the thermal-oxidative aging of asphalt, and reduces the production level of harmful volatiles through the thermal-oxidative ageing after EG/MH/CaCO3 is added into asphalt in the recommended content of 10 wt.%. EG plays a synergistic role with MH and CaCO3 nanoparticles to prevent the sequence responses, inhibiting the thermal-oxidative ageing of asphalt.Exposure to sunshine and exper