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An unprecedented molecular 2Fe-2As precursor complex was synthesized and transformed under soft reaction conditions to produce an active and long-term stable nanocrystalline FeAs material for electrocatalytic water oxidation in alkaline media. The 2Fe2As-centred β-diketiminato complex, having an unusual planar Fe2As2 core structure, results from the salt-metathesis reaction of the corresponding β-diketiminato FeIICl complex and the AsCO- (arsaethynolate) anion as the monoanionic As- source. The as-prepared FeAs phase produced from the p